MDI (4,4-Diphenylmethane Diisocyanate) High-Purity Isocyanate

High-purity MDI (4,4-MDI) aromatic isocyanate for PU elastomers, TPU, microcellular foams, adhesives and coatings — purity >=99.5%, NCO >=31.8%, low chlorine.

MDI (4,4′-diphenylmethane diisocyanate) is a high-purity aromatic isocyanate — the key reactive component (the “B / black material”) that reacts with polyols to build polyurethane. With purity ≥ 99.5% and NCO ≥ 31.8%, this refined MDI delivers excellent mechanical strength, durability and chemical stability for PU elastomers, TPU, microcellular foams, adhesives and coatings. Low chlorine and low colour for consistent, high-performance systems.

≥ 99.5%
purity
(GC)
≥ 31.8%
NCO
content
≤ 30
Colour
(Pt–Co)
~30
Viscosity
mPa·s (25 °C)
< 10
hydrolysable Cl
ppm

Key Features

High purity & NCO
≥ 99.5% purity and ≥ 31.8% NCO for strong, consistent crosslinking.
Excellent mechanical strength
Produces tough, durable PU elastomers and TPU with high tensile and tear.
Low chlorine & colour
Hydrolysable Cl < 10 ppm and colour ≤ 30 for clean, stable reactions.
Low viscosity
~30 mPa·s for easy metering and mixing with polyols.
Versatile building block
The MDI component for elastomers, TPU, adhesives, coatings and foams.
Reliable supply
Consistent batches with COA, packed and palletised for export.

Applications

MDI isocyanate drum
MDI Isocyanate (B Component)
MDI isocyanate steel drums
Drums & Bulk Supply
MDI isocyanate pails and drums
Pails & Drums
MDI isocyanate container export loading
Global Export Loading

Used to produce: PU & TPU elastomers, microcellular & integral-skin foams, structural adhesives and sealants, PU coatings and dispersions, and as the MDI reactive component in two-component PU systems.

Technical Specifications

Item Specification Standard
Purity ≥ 99.5% GC
NCO content ≥ 31.8% GB 12009.4
Colour (Platinum–Cobalt) ≤ 30 GB 3143
Freezing point ≤ 25 °C GB 7533
Density (20 °C) ~ 1.07 g/cm³ GB 4472
Flash point ~ 210 °C GB/T 261
Viscosity (25 °C) ~ 30 mPa·s GB 12009.3
Hydrolysable chlorine < 10 ppm Internal
Total chlorine ≤ 1000 ppm Internal

Typical values for reference, not a binding specification. Full TDS & MSDS on request.

MDI vs. HDI

MDI (this product) — aromatic
High reactivity and strength for elastomers, TPU, foams and adhesives. Cost-effective workhorse isocyanate.
HDI — aliphatic
Non-yellowing, for UV-stable clear-coats and paints — see our HDI isocyanate.

Packaging, Storage & Handling

Packaging
Supplied in sealed steel drums; palletised for export. Bulk on request.
Storage
Keep containers tightly sealed and dry — MDI reacts with moisture and can freeze below 25 °C (re-melt gently and mix before use). Store cool, indoors.
Handling & Safety
Use with adequate ventilation and PPE; avoid eye/skin contact and vapour. Full MSDS on request.

Explore More PU Materials

Why BlendPolyol

10+ years in PU raw materials
Specialised blended-polyol, isocyanate & PU systems supplier worldwide.
Consistent quality
High purity, low chlorine and low colour, batch-to-batch.
One-stop polyol + isocyanate
Matched polyols and systems for complete PU formulations.
Global export & fast reply
Export to EU, Latin America, Asia and beyond — we respond within 24 hours.

From Sample to Bulk Order

1. Share your system
Tell us the PU application and polyol — we confirm the MDI grade and ratio.
2. Sample & validate
Trial batches with TDS, MSDS and COA for your tests.
3. Scale to bulk
Confirm the grade and order in bulk with flexible MOQ and tiered lead times.

Frequently Asked Questions

Is this pure MDI or polymeric MDI?This is high-purity 4,4′-MDI (purity ≥ 99.5%, NCO ≥ 31.8%) for elastomers, TPU, microcellular foams, adhesives and coatings — tell us your application and we confirm the right grade.
Why does MDI freeze?Pure MDI solidifies below ~25 °C. Re-melt gently (warm, sealed) and mix thoroughly before use; avoid moisture during handling.
MDI or HDI for my product?MDI (aromatic) for strength and cost in elastomers, foams and adhesives; HDI (aliphatic) for non-yellowing clear-coats and paints.
Do you provide documentation?Yes — TDS, MSDS and per-batch COA; request a sample and we reply within 24 hours.
Need MDI isocyanate for your PU system?
Get grade confirmation, full TDS & MSDS, and a sample — with matched polyols if you need them.
✓ Purity ≥ 99.5%✓ TDS · MSDS · COA✓ Reply within 24 h

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